Aston Villa secured a 1-0 victory against Lille in the Europa League, while other matches saw Bologna draw with AS Roma and Porto win against VfB Stuttgart.
Wolverhampton Wanderers defeated Aston Villa 2-0 in the Premier League, with goals from Joao Gomes and Rodrigo Gomes, to avoid becoming the worst side in Premier League history.
The winners of the tie will face Real Sociedad or Athletic Bilbao in the final. Real Sociedad hold a 1-0 advantage ahead of their second leg in San Sebastian on March 4.
Barcelona missed the chance to reclaim the LaLiga summit after suffering a 2-1 derby defeat to Girona, who roared back in the second half to leave Real Madrid top of the table.
IMAGES from Premier League matches played on Sunday.
Stuttgart stumble to 1-1 against Union, miss out on top three
Christensen, Rashford on target as Barcelona beat Guadalajara in Copa del Rey
Aston Villa secured a 2-1 victory at Basel on Thursday, with goals from Evann Guessand and Youri Tielemans keeping their Europa League campaign on a strong footing.
Arsenal re-established their five-point lead at the top of the Premier League with a 2-0 home win against Brentford on Wednesday and for the second evening running the goals flowed as Aston Villa won 4-3 in a thriller at Brighton and Hove Albion.
Arsenal maintained a searing pace at the top of the Premier League with a straightforward 2-0 win at Burnley, while Liverpool snapped a dreadful four-match losing run with a 2-0 victory over Aston Villa to climb provisionally to third.
Cash on target as Villa hand Man City their first defeat since August
Ter Stegen back as Barcelona captain after signing LaLiga medical authorisation
Rashford, one of Europe's top talents before falling out of favour at United and spending the latter part of last season on loan at Aston Villa, joins a stellar attacking cast featuring Robert Lewandowski, Raphinha, Dani Olmo and Ferran Torres.
Nine players from treble-winning Paris St Germain have been nominated for the men's Ballon d'Or this year along with the club's coach Luis Enrique as France Football announced the list of nominees on Thursday.
Barcelona manager Hansi Flick was upset over several refereeing decisions in his side's 4-3 loss at Inter Milan that stopped the Catalans reaching their first Champions League final in a decade after an extra-time goal by home substitute Davide Frattesi.
Spain face Ronald Koeman's Netherlands away on Thursday before returning home for the second-leg on March 23.
'We have to move on and go ahead, it's our job. It's an important situation for the club to advance in the competition and we want to do well to honour him.'
Striker Robert Lewandowski scored a first-half penalty to give Barcelona a hard-fought 1-0 home win over Rayo Vallecano.
Atletico Madrid clawed back from two goals down to rescue a last-gasp 4-4 draw at Barcelona in a rip-roaring battle in the first leg of their Copa del Rey semi-final on Tuesday.
Barcelona came from an early goal down to beat Real Madrid 5-2 in the Spanish Super Cup final on Sunday
A round-up of Wednesday's UEFA Champions League last-16 first leg matches.
Barcelona will go to the international break on top of the standings on a perfect 12 points from four games, five ahead second-placed Villarreal and seven clear of bitter rivals Real Madrid
Barcelona captain Raphinha scored twice as they returned to winning ways in LaLiga for the first time in a month with a 5-1 victory at Mallorca on Tuesday.
Spain manager Luis de la Fuente left Barcelona's 17-year-old defender Pau Cubarsi and midfielders Marcos Llorente and Aleix Garcia out of his 26-man squad
Barcelona manager Hansi Flick has no complaints over his squad and fully trusts the club, the German said on the eve of Saturday's LaLiga opening clash at Valencia.
IMAGES from the Premier League matches played on Saturday.
Moises Caicedo's blistering second-half strike cancelled out a Bruno Fernandes penalty as Chelsea salvaged a 1-1 draw with Manchester United on Sunday.
Robert Lewandowski smashed home a rebound to earn Barcelona a 2-1 win against Athletic Bilbao in an absorbing LaLiga clash on Saturday.
Kareena says hi... Tisca has fun in sarson ka khet... Preity wears a happy smile...
Croatian forward Ante Budimir scored twice to help Osasuna earn a shock 4-2 home win over leaders Barcelona.
Robert Lewandowski's brace earned depleted Barcelona a 2-1 comeback win at Valencia
A fan invasion in the opening match of the Olympic football tournament between Argentina and Morocco on Wednesday caused chaos, with Argentina eventually beaten 2-1 following a VAR review after play was suspended with the score tied at 2-2.
India's hopes of redeeming some pride in the junior men's hockey World Cup remained only a dream as they lost 1-3 to Spain in the bronze medal playoff in Kuala Lumpur on Saturday.
A first-half penalty earned Lille a shock 1-0 home victory over holders Real Madrid in the Champions League group phase on Wednesday.
How will Russian athletes be cleared to compete at Paris 2024?
Kylian Mbappe scored twice in the second half to help his side to a 4-1 comeback win at 10-man Barcelona
Summary of the Europa League semi-final matches played on Thursday.
India will battle it out against the likes of South Korea, Malaysia, Pakistan, Japan and China in the Asian Champions Trophy.
Manchester United's Alejandro Garnacho scored with a magical overhead kick in the third minute to send the visitors on their way to a 3-0 victory over an Everton team already reeling in their first Premier League game after being docked 10 points.
Luis Enrique was sacked as Spain's coach on Thursday after the team's elimination in the last 16 at the World Cup.